Digging this up from way beyond the grave, but it was the top hit on Google, so thought I'd add my method. I have a preset I use for burning full-size JPGs. If you choose "Export To: Specific Folder," choose the folder you'd like to default to (for instance "Pictures" on your separate drive), then switch to "Export To: Choose folder later," and save your preset, it should always default to that folder you chose.
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